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This rate constant is approximately 10 times higher than the previously reported rate constant for benzyl alcohol oxidation by [Ru IV (tpy)(bpz)(O)] 2+ (tpy=2,2′,2″-terpyridine, bpz=2,2′-bipyrazine) at pH 11, 195 probably due to a greater driving force given the reduction potentials for [Ru 3 IV,IV,III O(Ac) 6 (py) 2 (O)] + ( E 0 =1.1 V at pH 6.7) and [Ru IV (tpy)(bpz)(O)] 2+ ( E 0 =0.90 V at pH 11)